3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA + CoASH => chenodeoxycholoyl-CoA (3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA) + propionyl CoA 3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA and CoASH react to form chenodeoxycholoyl-CoA (3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA) and propionyl CoA. This reaction, in the peroxisomal matrix, is catalyzed by peroxisomal thiolase 2 (sterol carrier protein 2). Authored: Jassal, B, 2007-01-19 10:34:59 EC Number: 2.3.1.154 Edited: D'Eustachio, P, 2007-02-17 19:40:28 Pubmed10706581 Pubmed12543708 Pubmed1703300 Reactome Database ID Release 43193533 Reactome, http://www.reactome.org ReactomeREACT_10103 Reviewed: D'Eustachio, P, 2007-04-30 14:43:26 Thiolysis of 3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA yields chenodeoxycholoyl-CoA (3alpha,7alpha-dihydroxy-5beta-cholan-24-one-CoA) and propionyl CoA