has functional parent oleandomycin macrolide antibiotic polyketide epoxide troleandomycin (3R,5R,6S,7R,8R,11R,12S,13R,14S,15S)-12-[(4-O-acetyl-2,6-dideoxy-3-O-methyl-alpha-L-arabino-hexopyranosyl)oxy]-14-{[2-O-acetyl-3,4,6-trideoxy-3-(dimethylamino)-beta-D-xylo-hexopyranosyl]oxy}-5,7,8,11,13,15-hexamethyl-4,10-dioxo-1,9-dioxaspiro[2.13]hexadecan-6-yl acetate 813.451 813.96840 A semi-synthetic macrolide antibiotic obtained by acetylation of the three free hydroxy groups of oleandomycin. Troleandomycin is only found in individuals that have taken the drug. C41H67NO15 CAS:2751-09-9 CHEBI:32267 CHEBI:45735 CO[C@H]1C[C@H](O[C@H]2[C@H](C)[C@@H](O[C@@H]3O[C@H](C)C[C@@H]([C@H]3OC(C)=O)N(C)C)[C@@H](C)C[C@@]3(CO3)C(=O)[C@H](C)[C@@H](OC(C)=O)[C@@H](C)[C@@H](C)OC(=O)[C@@H]2C)O[C@@H](C)[C@@H]1OC(C)=O DrugBank:DB01361 Drug_Central:2769 HMDB:HMDB0015448 InChI=1S/C41H67NO15/c1-19-17-41(18-49-41)38(46)23(5)34(53-27(9)43)21(3)25(7)52-39(47)24(6)35(56-32-16-31(48-14)36(26(8)51-32)54-28(10)44)22(4)33(19)57-40-37(55-29(11)45)30(42(12)13)15-20(2)50-40/h19-26,30-37,40H,15-18H2,1-14H3/t19-,20+,21-,22+,23+,24+,25+,26-,30-,31-,32-,33-,34-,35-,36-,37+,40-,41+/m0/s1 KEGG:C12753 KEGG:D01322 LINCS:LSM-5510 LIPID_MAPS_instance:LMPK04000042 LQCLVBQBTUVCEQ-QTFUVMRISA-N Oleandocetine Oleandomycin triacetate Oleandomycin triacetyl ester PDBeChem:TAO PMID:24335510 PMID:24479850 PMID:24889073 PMID:24985121 PMID:25392348 PMID:25870103 Reaxys:77547 Triacetyloleandomycin Triacetyloleandomycinum Tribiocillina Triocetin Wikipedia:Troleandomycin chebi_ontology troleandomicina troleandomycin troleandomycine troleandomycinum acetate ester monosaccharide derivative semisynthetic derivative