has role macrolide antibiotic narbomycin (3R,5R,6S,7S,9R,11E,13R,14R)-14-ethyl-3,5,7,9,13-pentamethyl-2,4,10-trioxooxacyclotetradec-11-en-6-yl 3,4,6-trideoxy-3-(dimethylamino)-beta-D-xylo-hexopyranoside 12-Deoxypicromycin 509.335 509.67530 A macrolide antibiotic that is narbonolide having a 3,4,6-trideoxy-3-(dimethylamino)-beta-D-xylo-hexopyranosyl residue attached at position 6. It is biosynthesised by Streptomyces venezuelae. C28H47NO7 CAS:6036-25-5 CC[C@H]1OC(=O)[C@H](C)C(=O)[C@H](C)[C@@H](O[C@@H]2O[C@H](C)C[C@@H]([C@H]2O)N(C)C)[C@@H](C)C[C@@H](C)C(=O)\C=C\[C@H]1C CHEBI:29649 CHEBI:44624 InChI=1S/C28H47NO7/c1-10-23-15(2)11-12-22(30)16(3)13-17(4)26(19(6)24(31)20(7)27(33)35-23)36-28-25(32)21(29(8)9)14-18(5)34-28/h11-12,15-21,23,25-26,28,32H,10,13-14H2,1-9H3/b12-11+/t15-,16-,17+,18-,19+,20-,21+,23-,25-,26+,28+/m1/s1 KEGG:C11998 MetaCyc:CPD-13834 Narbomycin OXFYAOOMMKGGAI-JLTOUBQASA-N PDBeChem:NRB PMID:1133401 PMID:12089557 PMID:20695498 PMID:21959378 PMID:22168449 PMID:5439233 PMID:9778370 PMID:9831532 Patent:US2006234958 Patent:US6303767 Reaxys:65732 chebi_ontology enone monosaccharide derivative bacterial metabolite