has role 1,4-benzoquinones ansamycin carbamate ester organic heterobicyclic compound antimicrobial agent geldanamycin (4E,6Z,8S,9S,10E,12S,13R,14S,16R)-13-hydroxy-8,14,19-trimethoxy-4,10,12,16-tetramethyl-3,20,22-trioxo-2-azabicyclo[16.3.1]docosa-1(21),4,6,10,18-pentaen-9-yl carbamate 560.273 560.63590 An ansamycin consisting of a 19-membered macrocyle incorporating a benzoquinone ring and a lactam functionality. It shows antimicrobial activity against many Gram-positive and some Gram-negative bacteria. C29H40N2O9 CAS:30562-34-6 CHEBI:42670 CHEBI:5292 CO[C@H]1C[C@H](C)CC2=C(OC)C(=O)C=C(NC(=O)\C(C)=C\C=C/[C@H](OC)[C@@H](OC(N)=O)\C(C)=C\[C@H](C)[C@H]1O)C2=O GELDANAMYCIN Geldanamycin InChI=1S/C29H40N2O9/c1-15-11-19-25(34)20(14-21(32)27(19)39-7)31-28(35)16(2)9-8-10-22(37-5)26(40-29(30)36)18(4)13-17(3)24(33)23(12-15)38-6/h8-10,13-15,17,22-24,26,33H,11-12H2,1-7H3,(H2,30,36)(H,31,35)/b10-8-,16-9+,18-13+/t15-,17+,22+,23+,24-,26+/m1/s1 KEGG:C11222 KNApSAcK:C00018795 PDBeChem:GDM PMID:21983172 PMID:21985437 PMID:22050565 PMID:22136518 PMID:22138446 PMID:22215907 PMID:22277058 PMID:22361388 QTQAWLPCGQOSGP-KSRBKZBZSA-N Reaxys:14205884 Wikipedia:Geldanamycin chebi_ontology